Chem 51A. Organic Chemistry. Lec 24. (English)
UCI Chem 51A Organic Chemistry (Fall 2014)
Lec 24. Organic Chemistry -- Factors that Affect the Rate of the SN1 Reaction
View the complete course: http://ocw.uci.edu/courses/chem_51a_organic_chemistry.html
Instructor: Susan King, Ph.D.
Description: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds.
Organic Chemistry (Chem 51A) is part of OpenChem: http://ocw.uci.edu/openchem
Recorded on December 3, 2014.
Index of Topics:
01:14 - Stereochemistry of the SN1 Reaction
03:16 - Factors that Affect the Rate of the SN1 Reaction
07:46 - The Structure of the Substrate
15:25 - Hyperconjugation
21:42 - The Structure of the Transition State: Hammond's Postulate
32:24 - The Effect of Solvent on the Rate of Reaction
37:29 - Benzylic Halides, Allylic Halides, Methoxymethyl Halides, Vinylic Halides, and Aryl Halides
44:09 - Vinylic and Aryl Halides do not undergo SN1 or SN2 Reactions
Required attribution: King, Susan Ph.D. Organic Chemistry 51A (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51a_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License.
- Susan King Ph.D.
Chem 51A. Organic Chemistry. Lec 24. by King, Susan is licensed under a Creative Commons Attribution-ShareAlike 3.0 United States License.