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Chem 51B. Lec 20. Organic Chemistry: Radicals (English)


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UCI Chem 51B Organic Chemistry (Winter 2013)
Lec 20. Organic Chemistry -- Radicals
View the complete course: http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html
Instructor: David Van Vranken, Ph.D.


License: Creative Commons BY-NC-SA
Terms of Use: http://ocw.uci.edu/info.
More courses at http://ocw.uci.edu


Description: This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. This video is part of a 26-lecture undergraduate-level course titled "Organic Chemistry" taught at UC Irvine by Professor David Van Vranken.

Organic Chemistry (Chem 51B) is part of OpenChem.
http://ocw.uci.edu/collections/open_chemistry.html


Recorded February 27. 2013.


Index of Topics:
00:17 - Pycnogenol
00:42 - What is Pycnogenol?
01:11 - Molecular Structure of Pycnogenol
03:22 - 14.8: Splitting by More than One Type of Proton
07:55 - 14.9: Time Dependence of H NMR Spectroscopy-Bond Rotation
09:42 - 14.9: Time Dependence of H NMR Spectroscopy

CHAPTER 15- Radicals
15:37 - 15.1: Radicals-Reactivity and Stability
21:04 - 15.1, 15.2: Reactions of Radicals-a specialized arrow symbol
24:55 - 15.3, 15.6, 15.7: Selective conversion of tertiary R-H to tertiary R-Br
29:35 - 15.4: Mechanism for Radical Bromination
36:26 - 15.8: Carbon radicals react on either end of the p orbital
42:15 - 15.10: Allylic Bromination
48:06 - 15.13: Anti-Markovnikov of HBr to H2C=CHR
50:39 - Chapter 15-Radical Summary


Required attribution: Vranken, David Van. Organic Chemistry 51B (UCI OpenCourseWare: University of California, Irvine),  http://ocw.uci.edu/courses/chem_51b_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License.


Author:
David Van Vranken
Title:
Professor
Department:
Chemistry
Creative Commons License
Chem 51B. Lec 20. Organic Chemistry: Radicals by David Van Vranken is licensed under a Creative Commons Attribution-ShareAlike 3.0 Unported License.
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