Chem 51C. Organic Chemistry. Lec. 04: Hydride Reagents and Addition to Carbonyls Part 2 (English)
UCI Chem 51C: Organic Chemistry (Spring 2015)
Lec 04. Organic Chemistry -- Hydride Reagents and Addition to Carbonyls -- Part 2
View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html
Instructor: Susan King, Ph.D.
Description: This is the third (and final) quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds.
Recorded April 6, 2015
Index of Topics:
00:24 - Alkoxide Leaving Group
01:39 - Points about Hydride Additions to Carbonyls
06:38 - LiAlH4 adds twice to Acid Chlorides
14:32 - Exactly Reducing Acid Chlorides to Aldehydes
17:59 - LiAlH4 Reduces Carboxylic Acids to Alcohols
26:43 - Converting a Carboxylic Acid to an Aldehyde
28:18 - Reducing Amides to Amines
38:33 - Stereochemistry of Carbonyl Reduction
40:21 - Chiral Reducing Agents
45:18 - Addition of Carbon Nucleophiles: Organometallic Reagents
Required attribution: King, Susan.Chem 51C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/by-sa/3.0/deed.en_US).
- Susan King
Chem 51C. Organic Chemistry. Lec. 04: Hydride Reagents and Addition to Carbonyls Part 2 by King, Susan is licensed under a Creative Commons Attribution-ShareAlike 3.0 United States License.