Chem 131A. Lec 21. Quantum Principles: Bigger Atoms, Hund's Rules and the Aufbau Principle (English)


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UCI Chem 131A Quantum Principles (Winter 2013)
Lec 21. Quantum Principles -- Bigger Atoms, Hund's Rules and the Aufbau Principle  --
View the complete course: http://ocw.uci.edu/courses/chem_131a_quantum_principles.html
Instructor: A.J. Shaka, Ph.D

License: Creative Commons BY-NC-SA
Terms of Use: http://ocw.uci.edu/info.
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Description: This course provides an introduction to quantum mechanics and principles of quantum chemistry with applications to nuclear motions and the electronic structure of the hydrogen atom. It also examines the Schrödinger equation and study how it describes the behavior of very light particles, the quantum description of rotating and vibrating molecules is compared to the classical description, and the quantum description of the electronic structure of atoms is studied.

Recorded on February 27, 2014.


Index of Topics:
1:22 Closed Shell Atoms
5:12 The Energy of an Atom
7:20 One and Two-Electron Integrals
8:47 Fock's Contribution
13:40 Optimized Orbitals Are Online
14:57 Who Was Roothaan?
18:48 Optimized Orbitals Are Online
22:17 The Most Stable Atom
24:45 Hund's Rules
29:22 The Basis of Rule #1
32:31 The Basis of Rule #2
33:54 The Basis of Rule #3
36:08 Predicting Stability
37:31 Practice Problem 27
39:02 The Aufbau Principle
43:29 The Periodic Table
45:20 A Cautionary Note
48:17 "Fission!"
50:09 Chemical Bonds


Required attribution: Shaka, A.J. Quantum Principles 131A (UCI OpenCourseWare: University of California, Irvine),  http://ocw.uci.edu/courses/chem_131a_quantum_principles.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License.


Author:
A.J. Shaka
Title:
Professor
Department:
Chemistry

Creative Commons License
Chem 131A: Quantum Principles by Athan J. Shaka, Ph.D. is licensed under a Creative Commons Attribution-ShareAlike 3.0 Unported License.

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